International Chemical Safety Cards

CYCLOHEXYLAMINE ICSC: 0245
World Health Organization (WHO) International Labour Organization (ILO) United Nations Environmental Programme (UNEP) European Commission National Institute for Occupational Safety and Health (NIOSH)
Cyclohexanamine
Aminocyclohexane
Aminohexahydrobenzene
Hexahydroaniline
C6H11NH2 / C6H13N
Molecular mass: 99.2
3 Flammable Liquid placard 8 Corrosive placard ICSC #    0245
CAS #     108-91-8
RTECS # GX0700000
UN #        2357
EC #         612-050-00-6
June 05, 2003 Validated
TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Flammable.
NO open flames, NO sparks, and NO smoking.
Powder, alcohol-resistant foam, water in large amounts, carbon dioxide.
EXPLOSION Above 28C explosive vapour/air mixtures may be formed.
Above 28C closed system, ventilation, and explosion-proof electrical equipment.
In case of fire: keep drums, etc., cool by spraying with water.
EXPOSURE
AVOID ALL CONTACT!
IN ALL CASES CONSULT A DOCTOR!
 •INHALATION Burning sensation. Cough. Laboured breathing. Nausea. Vomiting.
Ventilation, local exhaust, or breathing protection.
Fresh air, rest. Half-upright position. Refer for medical attention.
 •SKIN Redness. Pain. Skin burns.
Protective gloves. Protective clothing.
Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention.
 •EYES Redness. Pain. Severe deep burns.
Face shield or eye protection in combination with breathing protection.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
 •INGESTION Dizziness. Abdominal cramps. Burning sensation. Vomiting. Abdominal pain. Shock or collapse. Nausea.
Do not eat, drink, or smoke during work.
Rinse mouth. Do NOT induce vomiting. Refer for medical attention. Give plenty of water to drink.
SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
Evacuate danger area! Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Personal protection: self-contained breathing apparatus.
Fireproof. Separated from acids, oxidants , aluminium , copper , zinc , food and feedstuffs . Well closed.
Do not transport with food and feedstuffs.
C symbol
R: 10-21/22-34
S: 1/2-36/37/39-45
UN Hazard Class: 8
UN Subsidiary Risks: 3
UN Packing Group: II
SEE IMPORTANT INFORMATION ON BACK
ICSC: 0245 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards

CYCLOHEXYLAMINE ICSC: 0245
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PHYSICAL STATE; APPEARANCE:
COLOURLESS TO YELLOW LIQUID , WITH PUNGENT ODOUR.

PHYSICAL DANGERS:


CHEMICAL DANGERS:
The substance decomposes on burning producing toxic and corrosive fumes including nitrogen oxides . The substance is a strong base, it reacts violently with acid and is corrosive. Reacts violently with strong oxidants causing fire hazard. Attacks aluminium,copper,zinc.

OCCUPATIONAL EXPOSURE LIMITS:
TLV: 10 ppm as TWA; A4 (not classifiable as a human carcinogen); (ACGIH 2004).
MAK: 2 ppm, 8.2 mg/m;
Peak limitation category: I(2); Pregnancy risk group: C;
(DFG 2004).
OSHA PEL: none
NIOSH REL: TWA 10 ppm (40 mg/m3)
NIOSH IDLH: N.D. See: IDLH INDEX


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation, through the skin and by ingestion.

INHALATION RISK:
A harmful contamination of the air can be reached rather quickly on evaporation of this substance at 20C.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance is corrosive to the eyes, the skin and the respiratory tract. Corrosive on ingestion. The substance may cause effects on the central nervous system .

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
PHYSICAL
PROPERTIES
Boiling point: 134.5C
Melting point: -17.7C
Relative density (water = 1): 0.86
Solubility in water: miscible
Vapour pressure, kPa at 20C: 1.4
Relative vapour density (air = 1): 3.42
Relative density of the vapour/air-mixture at 20C (air = 1): 1.03
Flash point:
28C c.c.
Auto-ignition temperature: 293C
Explosive limits, vol% in air: 1.5-9.4
Octanol/water partition coefficient as log Pow: 1.4
Viscosity (Pa x s): 2.10 (20C)
ENVIRONMENTAL
DATA
Environmental Hazard placard The substance is harmful to aquatic organisms.
N O T E S
Card has been partly updated in October 2005. See sections Occupational Exposure Limits.
Transport Emergency Card: TEC (R)-80S2357

NFPA Code: H 2; F 3; R 0
ADDITIONAL INFORMATION


ICSC: 0245 CYCLOHEXYLAMINE
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.