International Chemical Safety Cards

d-ALLETHRIN ICSC: 0213
World Health Organization (WHO) International Labour Organization (ILO) United Nations Environmental Programme (UNEP) European Commission National Institute for Occupational Safety and Health (NIOSH)
(RS)-3-Allyl-2-methyl-4-oxocyclopent-2-enyl (1R)-cis-trans-chrysanthemate
2-Methyl-4-oxo-3-(2-propenyl)-2-cyclopenten-1-yl 2,2-dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylate
C19H26O3
Molecular mass: 302.4
6 Harmful - Stow Away from Foodstuffs placard 6 Poison placard ICSC #    0213
CAS #     584-79-2
RTECS # GZ1925000
UN #        3352
EC #         006-025-00-3
December 03, 2001 Validated
TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Combustible. Liquid formulations containing organic solvents may be flammable.
NO open flames.
Powder, AFFF, foam, carbon dioxide.
EXPLOSION

In case of fire: keep drums, etc., cool by spraying with water.
EXPOSURE
PREVENT GENERATION OF MISTS!

 •INHALATION Cough.
Ventilation, local exhaust, or breathing protection.
Fresh air, rest. Refer for medical attention.
 •SKIN Redness.
Protective gloves.
Remove contaminated clothes. Rinse and then wash skin with water and soap.
 •EYES Redness.
Safety goggles.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
 •INGESTION
Do not eat, drink, or smoke during work. Wash hands before eating.
Rinse mouth. Refer for medical attention.
SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
Personal protection: A/P2 filter respirator for organic vapour and harmful dust. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Do NOT wash away into sewer.
Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs . Keep in a well-ventilated room.
Do not transport with food and feedstuffs.
Note: C
Xn symbol
N symbol
R: 20/22-50/53
S: 2-36-60-61
UN Hazard Class: 6.1
UN Packing Group: III
SEE IMPORTANT INFORMATION ON BACK
ICSC: 0213 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards

d-ALLETHRIN ICSC: 0213
I

M

P

O

R

T

A

N

T


D

A

T

A
PHYSICAL STATE; APPEARANCE:
VISCOUS LIQUID.

PHYSICAL DANGERS:


CHEMICAL DANGERS:
The substance decomposes on heating above 400C producing irritating fumes .

OCCUPATIONAL EXPOSURE LIMITS:
TLV not established.


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of its aerosol and by ingestion.

INHALATION RISK:
No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20C.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance is irritating to the eyes , the skin and the respiratory tract .

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
PHYSICAL
PROPERTIES
Relative density (water = 1): 1.01
Solubility in water:
none
Flash point: 130C
Octanol/water partition coefficient as log Pow: 4.78
ENVIRONMENTAL
DATA
Environmental Hazard placard The substance is very toxic to aquatic organisms. Avoid release to the environment in circumstances different to normal use.
N O T E S
Carrier solvents used in commercial formulations may change physical and toxicological properties. Pynamin Forte is a trade name. Also consult publication Health and Safety Guide No. 24 Allethrins, and Environmental Health Criteria No. 87 Allethrins, of IPCS. Also consult ICSC 0228 (S-Bioallethrin), 0212 (Allethrin), 0227 (Bioallethrin). Card has been partly updated in October 2005. See section Emergency Response.
Transport Emergency Card: TEC (R)-61GT6-III
ADDITIONAL INFORMATION


ICSC: 0213 d-ALLETHRIN
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.