International Chemical Safety Cards

BIPHENYL ICSC: 0106
World Health Organization (WHO) International Labour Organization (ILO) United Nations Environmental Programme (UNEP) European Commission National Institute for Occupational Safety and Health (NIOSH)
Diphenyl
Phenylbenzene
Dibenzene
C12H10 / C6H5C6H5
Molecular mass: 154.2
9 U.S. Miscellaneous placard ICSC #    0106
CAS #     92-52-4
RTECS # DU8050000
UN #        3077
EC #         601-042-00-8
October 10, 2006 Validated
TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Combustible.
NO open flames.
water spray, foam, powder, carbon dioxide
EXPLOSION Finely dispersed particles form explosive mixtures in air.
Prevent deposition of dust; closed system, dust explosion-proof electrical equipment and lighting. Prevent build-up of electrostatic charges (e.g., by grounding).

EXPOSURE
PREVENT DISPERSION OF DUST!

 •INHALATION Cough. Nausea. Vomiting.
Avoid inhalation of fine dust and mist. Local exhaust or breathing protection.
Fresh air, rest. Refer for medical attention.
 •SKIN Redness.
Protective gloves.
Remove contaminated clothes. Rinse and then wash skin with water and soap.
 •EYES Redness. Pain.
Safety goggles or eye protection in combination with breathing protection if powder.
Rinse with plenty of water (remove contact lenses if easily possible).
 •INGESTION (Further see Inhalation).
Do not eat, drink, or smoke during work. Wash hands before eating.
Rinse mouth. Refer for medical attention.
SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
Personal protection: A/P2 filter respirator for organic vapour and harmful dust. Sweep spilled substance into sealable containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place. Do NOT let this chemical enter the environment.
Separated from food and feedstuffs, oxidants . Provision to contain effluent from fire extinguishing. Store in an area without drain or sewer access.
Do not transport with food and feedstuffs.
Xi symbol
N symbol
R: 36/37/38-50/53
S: 2-23-60-61
UN Hazard Class: 9
UN Packing Group: III
Signal: Warning
Health haz-Enviro
Causes eye irritation
May cause damage to liver and nervous system through prolonged or repeated exposure if inhaled
Very toxic to aquatic life
SEE IMPORTANT INFORMATION ON BACK
ICSC: 0106 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards

BIPHENYL ICSC: 0106
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PHYSICAL STATE; APPEARANCE:
WHITE CRYSTALS OR FLAKES , WITH CHARACTERISTIC ODOUR.

PHYSICAL DANGERS:
Dust explosion possible if in powder or granular form, mixed with air.

CHEMICAL DANGERS:
Reacts with oxidants .

OCCUPATIONAL EXPOSURE LIMITS:
TLV: 0.2 ppm as TWA; (ACGIH 2006).
MAK: skin absorption (H);
Carcinogen category: 3B;
(DFG 2006).
OSHA PEL: TWA 1 mg/m3 (0.2 ppm)
NIOSH REL: TWA 1 mg/m3 (0.2 ppm)
NIOSH IDLH: 100 mg/m3 See: 92524


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation, through the skin and by ingestion.

INHALATION RISK:
A harmful concentration of airborne particles can be reached quickly when dispersed

EFFECTS OF SHORT-TERM EXPOSURE:
The substance is irritating to the eyes , the skin and the respiratory tract .

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
The substance may have effects on the liver and nervous system , resulting in impaired functions .
PHYSICAL
PROPERTIES
Boiling point: 256C
Melting point: 70C
Relative density (water = 1): 1.04
Solubility in water, g/100 ml at 20C: 0.0004
Vapour pressure, Pa at 25C: 1.19
Relative vapour density (air = 1): 5.3
Relative density of the vapour/air-mixture at 20C (air = 1): 1.0
Flash point: 113C c.c
Auto-ignition temperature: 540C
Explosive limits, vol% in air: 0.6 (at 111C) - 5.8 (at 166C)
Octanol/water partition coefficient as log Pow: 3.16/4.09
ENVIRONMENTAL
DATA
Environmental Hazard placard The substance is very toxic to aquatic organisms. Bioaccumulation of this chemical may occur along the food chain, for example in plants. It is strongly advised that this substance does not enter the environment.
N O T E S
Do NOT take working clothes home.
Transport Emergency Card: TEC (R)-90GM7-III
NFPA Code: H 1; F 1; R 0;
Card has been partially updated in November 2008: see Packaging & labelling.
ADDITIONAL INFORMATION


ICSC: 0106 BIPHENYL
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.