| |
Appendix B
Summary of Occupational Exposure Data
Table B-1. Exposures to general asphalt refinery workers during asphalt refinery operations
| |
|
Samples |
Concentration (mg/m3) |
|
| Occupation |
Source of exposure |
Number |
Type |
Range |
Geo. mean |
Ari. mean |
References |
| General asphalt refinery workers |
Vacuum distillation |
4* |
Total PAHs† |
0.0047-0.016 |
0.0082 |
0.0095 |
NIOSH 1980 |
| General asphalt refinery workers |
Asphalt processing (6 refineries) |
14* |
Total PAHs† |
0.0015-0.031 |
0.067 |
0.010 |
NIOSH 1983 |
| General asphalt refinery workers |
Deasphalting (1 refinery) |
4* |
Total PAHs† |
0.0014-0.041 |
0.12 |
0.021 |
|
| Operator |
|
2 |
Total PAHs† |
0.0034-0.021 |
0.0084 |
0.012 |
|
| Assistant operator |
|
3 |
Total PAHs† |
0.0025-0.050 |
0.14 |
0.025 |
|
| Bitumen loaders |
Outdoor bitumen refinery |
‡ |
Benzene solubles |
0.3-1.0 |
§ |
§ |
Claydon et al. |
| |
unit (bitumen at 170 to 210°C [338 to 410°F]) |
‡ |
Total particulates |
0.1-1.4 |
§ |
§ |
|
| Package fillers |
Indoor area (bitumen at 220°C [428°F] |
2 |
Total particulates |
0.20-0.32 |
0.25 |
0.23 |
Brandt et al. |
| Bitumen loaders |
Outdoor bitumen refinery unit (bitumen at 170 to 210°C [338 to 410°F]) |
4 |
Total particulates |
0.7-2.9 |
§ |
1.4 |
|
| |
|
4 |
Benzene solubles |
<0.1-1.0 |
§ |
0.4 |
|
| |
|
4 |
Total PAHs† |
3.8-95 |
§ |
33 |
|
| Operator |
|
11 |
Total particulates |
<0.03-8.2 |
0.17 |
0.88 |
Hicks 1995 |
| |
|
11 |
Benzene solubles |
0.034-1.9 |
0.14 |
0.42 |
|
| Assistant operator |
Asphalt refinery/terminal (temperature of product at fume source ranged from 160 to 375°C[320 to 707°F]) |
9 |
Total particulates |
<0.03-0.49 |
0.18 |
0.25 |
|
| |
|
9 |
Benzene solubles |
<0.066-0.32 |
0.11 |
0.13 |
|
| |
|
4 |
Total particulates |
0.17-0.26 |
0.22 |
0.23 |
|
| |
|
4 |
Benzene solubles |
<0.062-0.43 |
0.15 |
0.21 |
|
| |
|
10 |
Total particulates |
<0.026-14 |
0.29 |
1.6 |
|
| |
|
10 |
Benzene solubles |
0.038-13 |
0.29 |
1.6 |
|
| Maintenance /administration |
Asphalt refinery/terminal (temperature of produce at fume source ranged from 160 to 375°C[320 to 707°F]) |
6 |
Total particulates |
<0.032-0.77 |
0.17 |
0.29 |
|
| |
|
6 |
Benzene solubles |
0.011-0.22 |
0.076 |
0.1 |
|
| Utility worker |
|
4 |
Total particulates |
<0.024-0.062 |
0.039 |
0.043 |
|
| |
|
4 |
Benzene solubles |
<0.054-1.1 |
0.3 |
0.49 |
|
Abbreviations: Ari. mean=arithmetic mean; Geo. mean=geometric mean.
*Area air samples. All remaining samples were personal-breathing-zone air samples.
†The sampling and analytical methods used for measuring PAH concentrations may vary between studies, and results may not be directly comparable.
‡Number of samples collected not available.
§Information not provided.
NOTE: Sampling periods ranged from 6 to 8 hours. Results shown are time-weighted averages.
NOTE: Solvents such as cyclohexane and acetonitrile have been used in place of benzene to measure the soluble fraction of a particular matrix. Because the extraction ability of these solvents varies, results are not comparable.
Table B-2. Exposures during road paving operations
| |
|
Samples |
Exposure concentration (mg/m3) |
|
| Occupation |
Source of exposure |
Number |
Type |
Range |
Geo. mean |
Ari. mean |
References |
| Screedman, rakerman, foreman, roller operator |
Road paving using an asphalt mix |
215 |
Total particulates |
* |
* |
0.3-0.7 |
Byrd and Mikkelsen 1979 |
| Paver operator |
|
72 |
Total particulates |
* |
* |
1.1 |
|
| Surface dressing worker |
Hot asphalt cutback surface (cutback at 135°C [275 °F]) |
9 |
Total particulates |
* |
* |
0.8 |
|
| Asphalt cement pavers |
|
17 |
Total particulates |
<0.1-1.2 |
* |
0.3 |
Virtamo et al. 1979 |
| |
|
1 |
Cyclohexane solubles |
* |
0.3 |
0.3 |
|
| Course asphalt base worker |
|
10 |
Total particulates |
0.4-1.1 |
* |
0.6 |
|
| |
|
1 |
Cyclohexane solubles |
* |
0.6 |
0.6 |
|
| Mastic asphalt worker |
Road paving (asphalt temperatures ranged from 145 to 195°C [293 to 383°F]) |
16 |
Total particulates |
0.2-4.2 |
* |
1.7 |
|
| |
|
11 |
Cyclohexane solubles |
<0.1-2.7 |
* |
1.2 |
|
| Unknown |
|
18 |
Total particulates |
0.1-3.0 |
* |
1.0 |
|
| |
|
6 |
Cyclohexane solubles |
<0.1-1.3 |
* |
0.7 |
|
| Surface dressing worker |
|
4 |
Total particulates |
0.8-2.5 |
* |
1.7 |
|
| |
|
4 |
Cyclohexane solubles |
<0.1-0.4 |
* |
0.2 |
|
| Oil gravel worker |
|
8 |
Total particulates |
0.1-1.4 |
* |
0.6 |
|
| |
|
2 |
Cyclohexane solubles |
<0.1-0.5 |
0.22 |
0.3 |
|
| Paver operator |
Road paving (asphalt mix temperature ranged from 130 to 170°C [266 to 338°F]) |
14 |
Total particulates |
0.15-5.6 |
0.80 |
1.3 |
Puzinauskas 1980 |
| Rakerman |
|
7 |
Total particulates |
0.25-3.5 |
0.61 |
0.93 |
|
| Screedman |
|
7 |
Total particulates |
0.33-1.5 |
0.62 |
0.83 |
|
| Paver operator, screedman |
Road paving |
4† |
Total PAHs‡ |
0.0043-0.013 |
0.0075 |
0.0083 |
Malaiyandi et al. 1982 |
| Screed operator |
Sulfur-extended asphalt road construction |
1 |
Total particulates |
* |
4.5 |
4.5 |
Daniels and Kramkoski
1983 |
| Laborer |
|
2 |
Total particulates |
2.4-3.6 |
2.9 |
3 |
|
| Various paving workers |
Hot bitumen cutback (temperature ranged from 120 to 158°C [248 to 316°F]) |
8 |
Total particulates |
0.2-15 |
* |
2.6 |
Daniels and Kramkoski
1983 |
| |
|
7 |
Benzene solubles |
0.1-0.3 |
* |
0.2 |
|
| Surface dressing worker |
|
7 |
Total particulates |
0.2-1.5 |
* |
0.6 |
|
| |
|
4 |
Benzene solubles |
0.1-0.5 |
* |
0.2 |
|
| Pavers (smokers) |
Road paving with asphalt |
4 |
Total PAHs‡ |
0.00075-0.0031 |
0.0015 |
0.0017 |
Pozzoli et al. 1985 |
| Paver operator |
Road paving using bitumens |
5 |
Total particulates |
* |
* |
0.58 |
Monarca et al. 1987 |
| |
|
5 |
Cyclohexane solubles |
* |
* |
0.17 |
|
| Screedman |
|
12 |
Total particulates |
* |
* |
0.83 |
|
| |
|
12 |
Cyclohexane solubles |
* |
* |
0.16 |
|
| Screedman 1 (smoker) |
|
1 |
Total particulates |
* |
0.22 |
0.22 |
Gunkel 1989 |
| |
|
1 |
Benzene solubles |
* |
0.11 |
0.11 |
|
| Screedman 2 (nonsmoker) |
|
1 |
Total particulates |
* |
0.22 |
0.22 |
|
| |
|
1 |
Benzene solubles |
* |
0.13 |
0.13 |
|
| Luteman (nonsmoker) |
|
1 |
Total particulates |
* |
0.16 |
0.16 |
|
| |
|
1 |
Benzene solubles |
* |
* |
ND |
|
| Roller operator (nonsmoker) |
|
1 |
Total particulates |
* |
0.48 |
0.48 |
|
| |
|
1 |
Benzene solubles |
* |
* |
ND |
|
| Screedman 1 (smoker) |
|
1 |
Total particulates |
* |
0.14 |
0.14 |
|
| |
|
1 |
Benzene solubles |
* |
0.20 |
0.20 |
|
| Screedman 2 (nonsmoker) |
|
1 |
Total particulates |
* |
0.44 |
0.44 |
|
| |
|
1 |
Benzene solubles |
* |
0.41 |
|
|
| Luteman (nonsmoker) |
|
1 |
Total particulates |
* |
0.32 |
0.32 |
|
| |
|
1 |
Benzene solubles |
* |
0.38 |
0.38 |
|
| Roller operator (nonsmoker) |
|
1 |
Total particulates |
* |
0.33 |
0.33 |
|
| |
|
1 |
Benzene solubles |
* |
0.098 |
0.098 |
|
| |
|
1 |
Total particulates |
* |
0.90 |
0.90 |
|
| Paver operator (nonsmoker) |
|
1 |
Benzene solubles |
* |
0.76 |
0.76 |
|
| Foreman |
Paving operations temperature
of product at fume source ranged from 123 to 152 °C [253 to 306 °F]) |
2 |
Total particulates |
0.32-0.53 |
0.41 |
0.43 |
Hicks 1995 |
| |
|
2 |
Benzene solubles |
0.12-0.22 |
0.16 |
0.17 |
|
| Laborer |
|
7 |
Total particulates |
0.22-0.43 |
0.34 |
0.34 |
|
| |
|
7 |
Benzene solubles |
0.049-0.5 |
0.15 |
0.2 |
|
| Screedman |
|
10 |
Total particulates |
0.21-0.86 |
0.48 |
0.54 |
|
| |
|
10 |
Benzene solubles |
0.03-4.4 |
0.28 |
0.73 |
|
| Luteman |
|
5 |
Total particulates |
0.12-0.35 |
0.21 |
0.23 |
|
| |
|
5 |
Benzene solubles |
<0.078-0.33 |
0.14 |
0.16 |
|
| Roller operator |
|
5 |
Total particulates |
0.11-0.82 |
0.3 |
0.4 |
|
| |
|
5 |
Benzene solubles |
<0.071-2.5 |
0.42 |
0.77 |
|
| Spreader operator (screedman) |
|
8 |
Total particulates |
0.14-0.86 |
0.46 |
0.54 |
|
| |
|
8 |
Benzene solubles |
0.038-1.2 |
0.33 |
0.47 |
|
| Foreman |
Paving operation (temperature
of product at fume source ranged from 135 to 151 °C [275 to 304 °F]) |
3 |
Total particulates |
0.19-0.24 |
0.22 |
0.22 |
Zey 1992a |
| |
|
1 |
Benzene solubles |
* |
* |
ND |
|
| Screedman |
|
5 |
Total particulates |
0.05-0.26 |
0.18 |
0.15 |
|
| |
|
3 |
Benzene solubles |
ND-0.20 |
0.015 |
0.047 |
|
| |
|
2 |
Acetonitrile solubles |
* |
* |
ND |
|
| Raker |
|
6 |
Total particulates |
0.01-0.47 |
0.14 |
0.23 |
|
| |
|
4 |
Benzene solubles |
ND-0.35 |
0.008 |
0.2 |
|
| |
|
2 |
Acetonitrile solubles |
* |
* |
ND |
|
| Roller |
|
6 |
Total particulates |
0.10-1.21 |
0.28 |
0.388 |
|
| |
|
4 |
Benzene solubles |
ND-0.12 |
0.0039 |
0.03 |
|
| |
|
2 |
Acetonitrile solubles |
* |
* |
ND |
|
| Paver operator |
|
3 |
Total particulates |
0.09-0.29 |
0.19 |
0.21 |
|
| |
|
2 |
Benzene solubles |
0.08-0.1 |
0.089 |
0.09 |
|
| Foreman |
Paving operations (temperature
of product at fume source ranged from 135 to 158 °C [275 to 316 °F]) |
3 |
Total particulates |
ND-0.44 |
0.047 |
0.22 |
Zey 1992b |
| |
|
2 |
Benzene solubles |
* |
* |
ND |
|
| |
|
1 |
Acetonitrile solubles |
* |
* |
ND |
|
| Screedman |
|
6 |
Total particulates |
0.20-1.14 |
0.45 |
0.54 |
|
| |
|
4 |
Benzene solubles |
0.07-0.13 |
0.09 |
0.098 |
|
| |
|
2 |
Acetonitrile solubles |
ND-0.13 |
0.0089 |
0.015 |
|
| Raker/Laborer |
|
6 |
Total particulates |
0.24-4.17 |
0.69 |
1.2 |
|
| |
|
3 |
Benzene solubles |
0.08-0.18 |
0.14 |
0.14 |
|
| |
|
3 |
Acetonitrile solubles |
* |
* |
ND |
|
| Roller operator |
|
4 |
Total particulates |
0.32-0.84 |
0.46 |
0.49 |
|
| |
|
3 |
Benzene solubles |
0.07-0.07 |
0.07 |
0.07 |
|
| |
|
1 |
Acetonitrile solubles |
* |
* |
ND |
|
| Paver operator |
|
3 |
Total particulates |
0.24-0.74 |
0.50 |
0.50 |
|
| |
|
2 |
Benzene solubles |
0.07-0.18 |
0.11 |
0.13 |
|
| |
|
1 |
Acetonitrile solubles |
* |
* |
ND |
|
| Screedman/supervisor |
Paving operations (temperature
of product at fume source ranged from 123 to 198°C [253 to 388 °F]) |
2 |
Total particulates |
0.07-0.19 |
0.12 |
0.13 |
Zey 1992c |
| |
|
1 |
Benzene solubles |
* |
* |
ND |
|
| |
|
1 |
Acetonitrile solubles |
* |
* |
ND |
|
| Laborer/supervisor |
|
1 |
Total particulates |
* |
0.15 |
0.15 |
|
| |
|
1 |
Benzene solubles |
* |
* |
ND |
|
| Raker/laborer |
|
8 |
Total particulates |
0.09-0.48 |
0.22 |
0.28 |
|
| |
|
5 |
Benzene solubles |
0.07 |
0.004 |
0.026 |
|
| |
|
3 |
Acetonitrile solubles |
0.05 |
0.031 |
0.033 |
|
| Roller |
|
4 |
Total particulates |
0.06-0.16 |
0.11 |
0.11 |
|
| |
|
3 |
Benzene solubles |
* |
* |
ND |
|
| |
|
1 |
Acetonitrile solubles |
* |
* |
ND |
|
| Paver operator |
|
3 |
Total particulates |
0.13-0.21 |
0.16 |
0.17 |
|
| |
|
2 |
Benzene solubles |
0.07-0.07 |
0.07 |
0.07 |
|
| |
|
1 |
Acetonitrile solubles |
* |
0.05 |
0.05 |
|
Abbreviations: Ari.mean=arithmetic mean; Geo. mean=geometric mean; ND=not detected. *Information not provided.
†Area air samples. All remaining samples were personal-breathing-zone air samples.
‡The sampling and analytical methods used for measuring PAH concentrations may vary between studies, and results may not be directly comparable.
NOTE: Sampling periods ranged from 6 to 8 hours. Results shown are time-weighted averages. NOTE: Solvents such as cyclohexane and acetonitrile have been used in place of benzene to measure the soluble fraction of a particular matrix. Because the extraction ability of these solvents varies, results are not comparable.
Table B-3. Exposures during hot-mix asphalt preparation
| |
|
Samples |
Exposure concentration (mg/m3) |
|
| Occupation |
Source of exposure |
Number |
Type |
Range |
Geo. mean |
Ari. mean |
References |
| Not specified |
Preparation of hot-mix asphalt |
8 |
Total particulates |
0.5-7.2 |
* |
* |
Puzinauskas and Corbett 1975 |
| |
|
8† |
Benzene solubles |
0.2-5.4 |
* |
* |
|
| Man in control cabin and operator on hot-mix asphalt storage bins |
Asphalt plants (2) |
* |
Total particulates |
ND-1.7 |
* |
0.7 |
Byrd and Mikkelsen
1979 |
| Loader/operator |
Hot-mix asphalt preparation
(temperature of product at fume source ranged from 129 to 170°C [264 to 338 °F]) |
9 |
Total particulates |
0.16-6.0 |
1.2 |
1.8 |
Hicks 1995 |
| |
|
9 |
Benzene solubles |
0.033-1.7 |
0.16 |
0.33 |
|
| Groundman |
|
9 |
Total particulates |
0.17-1.4 |
0.53 |
0.61 |
|
| |
|
9 |
Benzene solubles |
0.062-0.43 |
0.19 |
0.23 |
|
| Plant operator |
|
6 |
Total particulates |
0.1-1.5 |
0.58 |
0.79 |
|
| |
|
6 |
Benzene solubles |
0.026-0.28 |
0.13 |
0.16 |
|
| Laborer |
|
5 |
Total particulates |
0.2-1.5 |
1.5 |
4.0 |
|
| |
|
5 |
Benzene solubles |
0.011-0.22 |
0.069 |
0.1 |
|
| Foreman/supervisor |
|
4 |
Total particulates |
0.27-1.1 |
0.53 |
0.61 |
|
| |
|
4 |
Benzene solubles |
<0.065-1.4 |
0.28 |
0.5 |
|
Abbreviations: Ari. mean=arithmetic mean; Geo. mean=geometric mean; ND=not detected. *Information not provided.
†Area air samples. All remaining samples were personal-breathing-zone air samples.
‡Number of samples collected not available.
NOTE: Sampling periods ranged from 6 to 8 hours. Results shown are time-weighted averages. NOTE: Solvents such as cyclohexane and acetonitrile have been used in place of benzene to measure the soluble fraction of a particular matrix. Because the extraction ability of these solvents varies, results are not comparable.
Table B-4. Exposures during roofing operations
| |
|
Samples |
Exposure concentration (mg/m3) |
|
| Occupation |
Source of exposure |
Number |
Type |
Range |
Geo. mean |
Ari. mean |
References |
| Hot asphalt machine operator/carrie |
Roofing operation |
6 |
Cyclohexane solubles |
<0.02-0.19 |
0.050 |
0.082 |
Hervin and Emmett
1976 Brown and Fajen 1977a |
| Kettleman, felt layer |
Asphalt heating and mopping |
1 |
Benzene solubles |
* |
0.75 (f) |
0.75(f) |
|
| |
|
|
|
|
0.04(s) |
<0.04(s) |
|
| Felt layer |
Asphalt heating and mopping |
2 |
Benzene solubles |
0.35-1.3(f) |
0.67(f) |
0.825(f) |
|
| |
|
|
|
<0.04-0.23(s) |
0.096(s) |
0.14(s) |
|
| Foreman mopper |
|
1 |
Benzene solubles |
* |
4.9(f) |
0.49(f) |
|
| |
|
|
|
* |
0.12(s) |
0.12(s) |
|
| Felt tacker |
|
1 |
Benzene solubles |
* |
1.1(f) |
1.1(f) |
|
| |
|
|
|
|
0.16(s) |
0.16(s) |
|
| Kettleman |
|
4† |
Benzene solubles |
170-420(f) |
245(f) |
260(f) |
|
| |
|
|
|
<0.17-1.1(s) |
0.34(s) |
0.47(s) |
|
| Felt layer |
Asphalt heating and mopping |
2 |
Benzene solubles |
0.08-0.78(f) |
0.25(f) |
0.43(f) |
Brown and Fajen 1977b |
| |
|
|
|
<0.04-0.35(s) |
0.12(s) |
0.20(s) |
|
| Foreman |
|
1 |
Benzene solubles |
* |
2.1(f) |
2.1(f) |
|
| |
|
|
|
|
0.15(s) |
0.15(s) |
|
| Felt machine operator,mopper |
Application of hot roofing asphalt |
2 |
Benzene solubles |
0.17-2.5(f) |
0.65(f) |
1.3(f) |
Brown and Fajen 1977c |
| |
|
|
|
0.22-0.47(s) |
0.32(s) |
0.35(s) |
Brown and Fajen 1977c |
| Hot asphalt carrier |
|
1 |
Benzene solubles |
* |
0.57(f) |
0.57(f) |
|
| |
|
|
|
* |
0.16(s) |
0.16(s) |
|
| Mopper |
|
1 |
Benzene solubles |
* |
0.38(f) |
0.38(f) |
|
| |
|
|
|
* |
<0.04(s) |
<0.04(s) |
|
| Felt layer |
|
1 |
Benzene solubles |
* |
0.17(f) |
0.17(f) |
|
| |
|
|
|
* |
0.08(s) |
0.08(s) |
|
| Asphalt tank operator |
|
1 |
Benzene solubles |
|
<0.11(f&s) |
<0.11(f&s) |
|
| Kettleman |
Type III roofing asphalt |
6 |
Total particulates |
1.3-12 |
2.6 |
3.7 |
Merz and Weisgerber
1977 |
| |
|
6 |
Benzene solubles |
0.91-6.9 |
1.8 |
2.3 |
|
| Mopper |
|
6 |
Total particulates |
1.1-8.4 |
2.9 |
3.6 |
|
| |
|
6 |
Benzene solubles |
0.68-6.5 |
2.1 |
2.6 |
|
| Paperman |
|
6 |
Total particulates |
0.35-3.3 |
1.2 |
1.5 |
|
| |
|
6 |
Benzene solubles |
0.50-2.4 |
0.8 |
1.1 |
|
| Kettleman |
Type III roofing asphalt a) low volatility |
3 |
Total particulates |
1.28-2.5 |
1.7 |
1.7 |
Puzinauskas 1979 |
| |
|
3 |
Benzene solubles |
0.91-1.9 |
1.3 |
1.4 |
|
| Mopper |
|
3 |
Total particulates |
1.7-8.4 |
3.2 |
4.2 |
|
| |
|
3 |
Benzene solubles |
6.6 |
2.5 |
3.1 |
|
| Paperman |
|
3 |
Total particulates |
0.35-2.0 |
0.77 |
1.0 |
|
| |
|
3 |
Benzene solubles |
0.25-1.7 |
0.60 |
0.81 |
|
| Kettleman |
b)high volatility |
3 |
Total particulates |
1.8-13 |
4.0 |
5.7 |
|
| |
|
3 |
Benzene solubles |
1.4-6.9 |
2.5 |
3.3 |
|
| Mopper |
|
3 |
Total particulates |
1.1-4.5 |
2.6 |
3.1 |
|
| |
|
3 |
Benzene solubles |
0.68-3.4 |
1.7 |
2.0 |
|
| Paperman |
|
3 |
Total particulates |
0.88-3.3 |
1.8 |
2.1 |
|
| |
|
3 |
Benzene solubles |
0.57-2.4 |
1.2 |
1.4 |
|
| Mopper |
Spreading hot bitumen |
8 |
Total particulates |
0.2-3.4 |
* |
* |
Priha et al. 1980 |
| |
|
8 |
Cyclohexane solubles |
0.29-2.9 |
|
|
|
| Mopper and kettleman |
Asphalt roofing |
6* |
Total PAHs‡ |
0.015-0.11 |
0.023 |
0.033 |
Malaiyandi et al. 1982 |
| Kettleman |
Asphalt heating and mopping |
1 |
Cyclohexane solubles |
* |
0.28 |
0.28 |
Tharr 1982a |
| Mopper |
|
2 |
Cyclohexane solubles |
0.16-0.17 |
0.17 |
0.17 |
|
| Laborer |
Tear-off operations of an old asphalt roof (petroleum pitch) |
9 |
Cyclohexane solubles |
0.09-2.3 |
0.22 |
0.47 |
Tharr 1982b |
| Paper roller |
Asphalt roofing |
2 |
Benzene solubles |
1.0-1.1 |
1.1 |
1.1 |
Reed 1983 |
| Mopper |
|
1 |
Benzene solubles |
* |
0.9 |
0.9 |
|
| Kettleman |
|
2 |
Benzene solubles |
1.2-1.2 |
1.2 |
1.2 |
|
| Kettleman |
Kettle emissions and bitman spreading |
2 |
Total particulates |
4.1-6.4 |
5.1 |
5.3 |
Brandt et al. 1985 |
| |
|
2 |
Benzene solubles |
3.5-5.4 |
4.3 |
4.5 |
|
| |
|
7 |
Total particulates |
0.5-1.7 |
* |
1.3 |
|
| |
|
7 |
Benzene solubles |
0.2-1.1 |
* |
0.7 |
|
| Roof-level workers (laborer,
mopper, carrier, etc.) |
Application of an asphalt built-up roof |
16 |
Acetonitrile solubles |
0.04-2.7 |
0.16 |
0.34 |
Carson 1986 |
| Ground-level workers(kettlemen) |
|
3 |
Acetonitrile solubles |
0.04-0.83 |
0.27 |
0.49 |
|
| Laborer |
Tear-off operations of an old asphalt roof (petroleum pitch) |
6 |
Total particulates |
0.76-2.8 |
1.72 |
1.9 |
Reed 1986 |
| |
|
6 |
Benzene solubles |
ND-0.32 |
0.0096 |
0.11 |
|
| Various (kettleman, laborer, etc.) |
Application of asphalt roof |
28 |
Benzene solubles |
ND-1.4 |
0.18 |
0.39 |
Zey et al. 1988 |
| Various (kettleman, laborer, etc.) |
Application of Koppers roof |
10 |
Benzene solubles |
ND-1.9 |
0.013 |
1.9 |
|
| Roofer |
Roofing operation (temperature of product at fume source from 163 to 316 °C [325 to 600 °F]) |
12 |
Total particulates |
0.04-2.2 |
0.36 |
0.58 |
Hicks 1995 |
| |
|
12 |
Benzene solubles |
0.011-1.7 |
0.19 |
0.45 |
|
| Laborer |
|
5 |
Total particulates |
0.21-0.91 |
0.38 |
0.47 |
|
| |
|
5 |
Benzene solubles |
0.17-0.62 |
0.3 |
0.34 |
|
| Mechanic |
|
7 |
Total particulates |
0.24-1.2 |
0.54 |
0.65 |
|
| |
|
7 |
Benzene solubles |
<0.078-1.8 |
0.26 |
0.49 |
|
| Felt machine operator |
|
7 |
Total particulates |
0.57-2.5 |
1.0 |
1.3 |
|
| |
|
7 |
Benzene solubles |
0.046-2.4 |
0.21 |
0.53 |
|
| Kettleman |
|
4 |
Total particulates |
0.36-1.6 |
1.0 |
1.2 |
|
| |
|
4 |
Benzene solubles |
0.14-1.2 |
0.67 |
0.89 |
|
| Mopper |
|
3 |
Total particulates |
0.27-1.2 |
0.51 |
0.63 |
|
| |
|
3 |
Benzene solubles |
<0.085-0.75 |
0.21 |
0.33 |
|
Abbreviations: Ari.mean=arithmetic mean; f=filter; Geo. mean=geometric mean; ND=not detected; s=sorbent tube.
*Information not provided.
† Area air samples. All remaining samples were personal-breathing-zone air samples.
‡Sampling and analytical methods used for measuring PAH concentrations may vary among studies, and these results may not be directly comparable.
NOTE: Sampling periods ranged from 6 to 8 hours. Results shown are time-weighted averages.
NOTE: Solvents such as cyclohexane and acetonitrile have been used in place of benzene to measure the soluble fraction of a particular matrix. Because the extraction ability of these solvents varies,
results are not comparable.
Table B-5. Exposures during manufacturing of roofing products
| |
|
Samples |
Exposure concentration (mg/m3) |
|
| Occupation |
Source of exposure |
Number |
Type |
Range |
Geo. mean |
Ari. mean |
References |
| Saturator operator |
Production of asphalt shingles and rolled roofing materials |
3 |
Total particulates |
2.2-7.3 |
4.9 |
5.6 |
Apol and Okawa 1977 |
| |
|
2 |
Cyclohexane solubles |
0.81-2.6 |
1.4 |
1.7 |
|
| Coater operator |
|
2 |
Total particulates |
14-15 |
14 |
14 |
|
| |
|
2 |
Cyclohexane solubles |
0.87-6.8 |
2.4 |
3.9 |
|
| Coater trainee |
|
2 |
Total particulates |
11-15 |
13 |
13 |
|
| |
|
2 |
Cyclohexane solubles |
0.30-2.3 |
0.84 |
1.3 |
|
| Press operator |
|
2 |
Total particulates |
6.1-32 |
14 |
19 |
|
| |
|
2 |
Cyclohexane solubles |
1.4-1.5 |
1.4 |
1.42 |
|
| Seal down operator |
|
2 |
Total particulates |
0.99-1.4 |
1.2 |
1.21 |
|
| |
|
2 |
Cyclohexane solubles |
0.43-1.2 |
0.71 |
0.81 |
|
| Foreman |
|
2 |
Total particulates |
5.3-6.3 |
5.8 |
5.8 |
|
| |
|
2 |
Cyclohexane solubles |
0.47-0.53 |
0.50 |
0.5 |
|
| Hallmark operation worker |
|
7 |
Total particulates |
0.96-2.16 |
1.6 |
1.6 |
|
| |
|
5 |
Cyclohexane solubles |
0.23-0.76 |
0.46 |
0.50 |
|
| Hallmark worker |
Production of asphalt shingles |
8 |
Total particulates |
0.38-5.2 |
1.0 |
1.4 |
Okawa and Apol 1977 |
| |
|
8 |
Cyclohexane solubles |
0.24-3.1 |
0.76 |
1.05 |
|
| Saturator operator |
Production of asphalt shingles and rolled roofing materials |
1 |
Total particulates |
|
2.4 |
2.4 |
Apol and Okawa 1978 |
| |
|
1 |
Cyclohexane solubles |
* |
0.76 |
0.76 |
|
| Coater |
|
2 |
Total particulates |
12-16 |
14 |
14 |
|
| |
|
2 |
Cyclohexane solubles |
0.21-1.1 |
0.47 |
0.64 |
|
| Wrapping machine operator |
|
1 |
Total particulates |
* |
1.4 |
1.40 |
|
| |
|
1 |
Cyclohexane solubles |
* |
0.77 |
0.77 |
|
| Lead man |
|
1 |
Total particulates |
* |
5.3 |
5.29 |
|
| |
|
1 |
Cyclohexane solubles |
* |
0.76 |
0.76 |
|
| Presser |
|
2 |
Total particulates |
8.3-22 |
13 |
15 |
|
| |
|
2 |
Cyclohexane solubles |
0.30-0.54 |
0.402 |
0.42 |
|
| Coater |
Production of asphalt shingles and rolled roofing materials |
2 |
Total particulates |
4.2-5.1 |
4.6 |
4.7 |
Okawa and Apol 1978a |
| |
|
2 |
Cyclohexane solubles |
3.3-3.9 |
3.6 |
3.6 |
|
| Cooling section operator |
|
2 |
Total particulates |
0.3-1.0 |
0.55 |
0.65 |
|
| |
|
2 |
Cyclohexane solubles |
0.7-1.6 |
1.06 |
1.2 |
|
| Machine tender |
|
2 |
Total particulates |
0.4-2.8 |
1.06 |
1.6 |
|
| |
|
2 |
Cyclohexane solubles |
0.6-1.8 |
1.039 |
1.2 |
|
| Saturator operator |
Production of asphalt shingles and rolled roofing materials |
1 |
Total particulates |
* |
1.0 |
1.0 |
Okawa and Apol 1978b |
| |
|
1 |
Cyclohexane solubles |
* |
2.1 |
2.1 |
|
| Coaterman |
|
1 |
Total particulates |
* |
2.1 |
2.1 |
|
| |
|
1 |
Cyclohexane solubles |
* |
0.22 |
0.22 |
|
| Slateman |
|
1 |
Total particulates |
* |
3.4 |
3.4 |
|
| |
|
1 |
Cyclohexane solubles |
* |
0.21 |
0.21 |
|
| Paper production workers (smokers) |
Asphalted paper production |
4 |
Total PAHs† |
0.0048-0.036 |
0.009 |
0.014 |
Pozzoli et al. 1985 |
| Paper production workers (nonsmokers) |
|
2 |
Total PAHs† |
0.0034-0.311 |
0.010 |
0.017 |
|
| Loader/asphalt handler |
Roofing manufacturing (temperature of product at fume source from 149 to 377 °C [300 to 710 °F]) |
6 |
Total particulates |
0.068-0.94 |
0.51 |
0.66 |
Hicks 1995 |
| |
|
6 |
Benzene solubles |
0.041-0.71 |
0.31 |
0.41 |
|
| Slate blend operator |
|
4 |
Total particulates |
1.1-13 |
3.9 |
5.6 |
|
| |
|
4 |
Benzene solubles |
0.013-0.94 |
0.077 |
0.27 |
|
| Coater operator |
|
8 |
Total particulates |
0.42-2.5 |
1.0 |
1.3 |
|
| |
|
8 |
Benzene solubles |
0.049-1.6 |
0.2 |
0.37 |
|
| Machine operator |
Roofing manufacturing (temperature of product at fume source from 149 to 377 °C [300 to 710°F]) |
8 |
Total particulates |
0.8-4.4 |
1.6 |
1.9 |
|
| |
|
8 |
Benzene solubles |
<0.071-3.6 |
0.55 |
1.5 |
|
| Press operator/cooling operator |
|
7 |
Total particulates |
0.55-11 |
2.6 |
4.8 |
|
| |
|
7 |
Benzene solubles |
<0.085-3.7 |
0.32 |
1.0 |
|
| Supervisor |
|
1 |
Total particulates |
* |
1.4 |
1.4 |
|
| |
|
1 |
Benzene solubles |
* |
0.32 |
0.32 |
|
Abbreviations: Ari. mean=arithmetic mean; Geo. mean=geometric mean.
*Information not provided.
†The sampling and analytical methods used for measuring PAH concentrations may vary between studies, and results may not be directly comparable.
NOTE: Sampling periods ranged from 6 to 8 hours. Results shown are time-weighted averages.
NOTE: Solvents such as cyclohexane and acetonitrile have been used in place of benzene to measure the soluble fraction of a particular matrix. Because the extraction ability of these solvents varies, results are not comparable
Table B-6. Exposures during flooring and waterproofing operations
| |
|
Samples |
Exposure concentration (mg/m3) |
|
| Occupation |
Source of exposure |
Number |
Type |
Range |
Geo. mean |
Ari. mean |
References |
| Brusher of felt interply adhesive |
Waterproofing of basements, kitchens, bathrooms, and corridors |
9 |
Total particulates |
1.1-32 |
* |
10.4 |
Ahonen et al. 1977 |
| |
|
5 |
Cyclohexane solubles |
0.8-28 |
* |
7.7 |
|
| Mixing operator (other possible exposures) |
Manufacturer of vinyl asbestos and asphalt asbestos floor covering |
6 |
Benzene solubles |
0.08-0.66 |
0.30 |
0.37 |
Belanger and Elesh 1979 |
| Spreader of hot bitumen and felt seaming |
Waterproofing of kitchens, bathrooms, and underground spaces |
15 |
Total particulates |
1.9-42 |
* |
18 |
Priha et al. |
| |
|
† |
Cyclohexane solubles |
0.3-39 |
* |
* |
|
| Spreader of hot bitumen and felt seaming |
Waterproofing of basements |
6 |
Total particulates |
1.6-13 |
* |
6.1 |
|
| |
|
|
Cyclohexane solubles |
1.6-11 |
* |
5.6 |
|
| Spreader |
Flooring-industrial asphalt mixture of bitumen, lime, sand, gravel, and coloring agent |
10 |
Carbon tetrachloride extracts |
8.2-237 |
* |
8.3 |
Claydon et al. |
| Tipper |
|
10 |
Carbon tetrachloride extracts |
3.1-260 |
* |
7.3 |
|
| Float finisher |
|
8 |
Carbon tetrachloride extracts |
1.7-214 |
* |
6.3 |
|
| Bucket carrier |
|
4 |
Carbon tetrachloride extracts |
0.5-5.5 |
* |
* |
|
| Bucket filler |
|
2 |
Carbon tetrachloride extracts |
3.1-4.2 |
3.6 |
* |
|
| Troweler |
Bitumen mastic on gymnasium floor |
2 |
Total particulates |
5.5-12 |
8.1 |
8.7 |
|
| Troweler |
|
2‡ |
Total particulates |
1.2-6.3 |
2.7 |
3.8 |
|
| |
|
4‡ |
Total particulates |
1.7-30 |
* |
* |
|
| Troweler |
Hand laying mastic containing 11% bitumen at 265-280°C [509-536 °F] |
1 |
Benzene solubles |
* |
10 |
10 |
|
| Tipper |
|
1 |
Benzene solubles |
* |
7.1 |
7.1 |
|
| Carrier |
|
1 |
Benzene solubles |
* |
11 |
11 |
|
| Kettleman |
|
1 |
Benzene solubles |
* |
2.9 |
2.9 |
|
| Bucket carrier, pourer (indoors) |
Mastic asphalt (265 to 280°C [509 to 536 °F]) |
5 |
Total particulates |
11-18 |
* |
13.3 |
Brandt et al. |
| |
|
5 |
Benzene solubles |
6.0-14 |
* |
8.8 |
|
| Kettleman (outside) |
|
4 |
Total particulates |
2.9-7.7 |
* |
4.4 |
|
| |
|
4 |
Benzene solubles |
2.0-5.0 |
* |
* |
|
| Troweler |
|
3 |
Total particulates |
11-18 |
* |
14 |
|
| |
|
3 |
Benzene solubles |
7.3-13 |
* |
10 |
|
Abbreviations: Ari. mean=arithmetic mean; Geo. mean=geometric mean.
*Information not provided.
†Number of samples collected not available.
‡Area air samples. All remaining samples were personal-breathing-zone air samples.
NOTE: Sampling periods ranged from 6 to 8 hours. Results shown are time-weighted averages. NOTE: Solvents such as cyclohexane and acetonitrile have been used in place of benzene to measure the soluble fraction of a particular matrix. Because the extraction ability of these solvents varies, results are not comparable.
|
|
|